{"id":9419,"date":"2022-08-10T07:47:55","date_gmt":"2022-08-10T07:47:55","guid":{"rendered":"https:\/\/www.szlaser.com\/?page_id=9419"},"modified":"2022-08-16T03:50:12","modified_gmt":"2022-08-16T03:50:12","slug":"ndyvo4-2","status":"publish","type":"page","link":"https:\/\/www.szlaser.com\/index.php\/wiki\/ndyvo4-2\/","title":{"rendered":"Brief Introduction to Nd:YVO4 Crystal"},"content":{"rendered":"<div class=\"fusion-fullwidth fullwidth-box fusion-builder-row-1 fusion-flex-container has-pattern-background has-mask-background nonhundred-percent-fullwidth non-hundred-percent-height-scrolling\" style=\"--awb-border-radius-top-left:0px;--awb-border-radius-top-right:0px;--awb-border-radius-bottom-right:0px;--awb-border-radius-bottom-left:0px;--awb-flex-wrap:wrap;\" ><div class=\"fusion-builder-row fusion-row fusion-flex-align-items-flex-start fusion-flex-content-wrap\" style=\"max-width:1331.2px;margin-left: calc(-4% \/ 2 );margin-right: calc(-4% \/ 2 );\"><div class=\"fusion-layout-column fusion_builder_column fusion-builder-column-0 fusion_builder_column_1_1 1_1 fusion-flex-column\" style=\"--awb-bg-size:cover;--awb-width-large:100%;--awb-margin-top-large:0px;--awb-spacing-right-large:1.92%;--awb-margin-bottom-large:20px;--awb-spacing-left-large:1.92%;--awb-width-medium:100%;--awb-order-medium:0;--awb-spacing-right-medium:1.92%;--awb-spacing-left-medium:1.92%;--awb-width-small:100%;--awb-order-small:0;--awb-spacing-right-small:1.92%;--awb-spacing-left-small:1.92%;\"><div class=\"fusion-column-wrapper fusion-column-has-shadow fusion-flex-justify-content-flex-start fusion-content-layout-column\"><div class=\"fusion-title title fusion-title-1 fusion-sep-none fusion-title-text fusion-title-size-one\"><h1 class=\"fusion-title-heading title-heading-left fusion-responsive-typography-calculated\" style=\"margin:0;--fontSize:32;line-height:1.3;\"><h1>Brief Introduction to <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> Crystal from Physical and Optical<\/h1><\/h1><\/div><div class=\"fusion-text fusion-text-1\"><p><a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> (neodymium-doped yttrium vanadate) crystal is a laser host crystal with excellent performance, suitable for making all-solid-state lasers pumped by laser diodes (LD). The crystal has the following characteristics: low laser threshold, high slope efficiency, large stimulated emission cross section, great absorption of pump light in a wide wavelength range, and single-mode tuning, high resistance to light damage. The latest progress shows that the combination of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span> <\/a>crystal and <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/nonlinear-crystals\/ktp\/\"><span style=\"color: #0000ff;\">KTP<\/span><\/a> crystal can be used to make high-power stable infrared, green or red lasers.<\/p>\n<\/div><div class=\"fusion-title title fusion-title-2 fusion-sep-none fusion-title-text fusion-title-size-one\"><h1 class=\"fusion-title-heading title-heading-left fusion-responsive-typography-calculated\" style=\"margin:0;--fontSize:32;line-height:1.3;\"># Physical and Optical Properties of Crystals<\/h1><\/div><div class=\"fusion-text fusion-text-2\"><p>The <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> crystal belongs to the tetragonal system and is a positive uniaxial crystal. <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> crystal has been widely recognized as a very important laser material since its inception in 1966. However, the researchers found that such crystals have defects such as scattering centers and absorption color centers, making it impossible to grow high-quality crystals of sizes suitable for flashlamp pumping. Fortunately, it has great absorption and gain to the diode radiation wavelength, large emission cross-section, and good polarization characteristics of the output laser, which are enough to mask the shortcomings of its small growth size. <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> crystal is a laser crystal material with excellent performance that is very suitable for laser diode pumping.<\/p>\n<p>Some of its characteristic parameters are given below:<br \/>\nAbsorption wavelength (nm): 808.5;<\/p>\n<p>Absorption coefficient (cm-1): 31.4 (\u03c0 polarization, 808nm);<br \/>\nEmission wavelength (nm): 1064.3;<\/p>\n<p>Emission cross section (cm2): 25\u00d710-19 (1064nm);<br \/>\nFluorescence lifetime (\u03bcs): 94 (1.22at.%);<\/p>\n<p>Refractive index (@1064nm): no=1.957, ne=2.165;<br \/>\nThermal light coefficient (\/K, @300K): dno\/dT=8.5\u00d710-6, dne\/dT=3.0\u00d710-6<\/p>\n<\/div><div class=\"fusion-title title fusion-title-3 fusion-sep-none fusion-title-text fusion-title-size-one\"><h1 class=\"fusion-title-heading title-heading-left fusion-responsive-typography-calculated\" style=\"margin:0;--fontSize:32;line-height:1.3;\"># Absorption and Divergence Properties of Crystals<\/h1><\/div><div class=\"fusion-text fusion-text-3\"><p>Since this crystal is naturally birefringent, its absorption of the pump light is polarization dependent. If the polarization direction of the pump light is consistent with the laser radiation direction, the absorption of the pump light is the strongest. Figure 1(a) is the absorption spectrum of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> crystal. It can be seen that the crystals exist between 800 and 900 nm<\/p>\n\n<script type=\"text\/javascript\">if(typeof(wpDataCharts)=='undefined'){wpDataCharts = {};}; wpDataCharts[1] = {render_data: 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Crystal Wiki] NdYVO4 Absorption Chart\",\"series\":[],\"height\":400,\"responsive_width\":1,\"hAxis\":{\"title\":\"\",\"direction\":\"1\"},\"vAxis\":{\"title\":\"\",\"direction\":\"1\",\"viewWindow\":{\"min\":\"\",\"max\":\"\"}},\"backgroundColor\":{\"fill\":\"\",\"strokeWidth\":0,\"stroke\":\"\",\"rx\":0},\"chartArea\":{\"backgroundColor\":{\"fill\":\"\",\"strokeWidth\":0,\"stroke\":\"\"}},\"fontSize\":\"\",\"fontName\":\"Arial\",\"curveType\":\"none\",\"crosshair\":{\"trigger\":\"\",\"orientation\":\"\"},\"orientation\":\"horizontal\",\"titlePosition\":\"out\",\"tooltip\":{\"trigger\":\"focus\"},\"legend\":{\"position\":\"right\",\"alignment\":\"end\"}},\"vAxis\":[],\"hAxis\":[],\"errors\":[],\"series\":[{\"label\":\"Intensity\",\"color\":\"\",\"orig_header\":\"newcolumn1\"}],\"group_chart\":false,\"show_grid\":true,\"type\":\"google_line_chart\"}, engine: \"google\", type: \"google_line_chart\", title: \"[Laser Crystal Wiki] NdYVO4 Absorption Chart\", container: \"wpDataChart_1\", follow_filtering: 0, wpdatatable_id: 385, group_chart: 0}<\/script>\n\n    <div id=\"wpDataChart_1\" class=\"google_line_chart\" style=\"width: 100%\"><\/div>\n\n<p>Two absorption peaks: 808.5nm and 879.8nm, respectively. On the other hand, the absorption coefficient of the crystal is larger for \u03c0-polarized pump light than for \u03c3-polarized pump light, and the absorption coefficient of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> in the \u03c0 direction is about 4 times that of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/laser-crystal\/nd-yag\/\"><span style=\"color: #0000ff;\">Nd:YAG<\/span><\/a>. Therefore, in order to make full use of the energy of the pump light, \u03c0-polarized pumping is usually used.<\/p>\n<p><a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> crystal not only has strong polarization absorption characteristics, but also has strong polarization radiation characteristics. The laser output is linearly polarized along the \u03c0 or \u03c3 direction, so that unnecessary thermal birefringence in the crystal can be avoided, which is also the biggest feature that distinguishes them from <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/laser-crystal\/nd-yag\/\"><span style=\"color: #0000ff;\">Nd:YAG<\/span><\/a> crystals. Figure 4-1b shows the emission spectrum of the crystal. It can be seen that its polarized emission along the \u03c0 direction is strong, and the emission cross section of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> is larger, which leads to the following results in practical applications: The average output power obtained by <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> is larger, and the light-to-light conversion efficiency is higher. high.<\/p>\n<p>In conclusion, <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> has the advantages of larger absorption coefficient, higher emission cross-section, polarization absorption and emission characteristics, larger absorption bandwidth, and insensitivity to the temperature change of the diode compared with the conventional <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/laser-crystal\/nd-yag\/\"><span style=\"color: #0000ff;\">Nd:YAG<\/span><\/a> crystal. Therefore, it is widely used in LD-pumped all-solid-state lasers. However, due to its large emission cross section and short upper energy level lifetime, the energy storage capacity of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> is far inferior to that of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/laser-crystal\/nd-yag\/\"><span style=\"color: #0000ff;\">Nd:YAG<\/span><\/a>, which is not conducive to the output of Q-switched pulses with high energy and high peak power. The advantages are only limited to the continuous wave output of high average power and high conversion efficiency. In addition, the thermal conductivity of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/ndyvo4\/\"><span style=\"color: #0000ff;\">Nd:YVO4<\/span><\/a> is very small, only half of that of <a href=\"https:\/\/www.szlaser.com\/index.php\/crystal\/laser-crystal\/nd-yag\/\"><span style=\"color: #0000ff;\">Nd:YAG<\/span><\/a>, so it is not conducive to the realization of high-power continuous wave output.<\/p>\n<\/div><div style=\"text-align:right;\"><a class=\"fusion-button button-flat fusion-button-default-size button-default fusion-button-default button-1 fusion-button-default-span fusion-button-default-type\" target=\"_self\" href=\"https:\/\/www.szlaser.com\/index.php\/wiki\/introduction-to-ktp-crystal\/\"><span class=\"fusion-button-text awb-button__text awb-button__text--default\">Introduction to KTP Crystal &gt;<\/span><\/a><\/div><\/div><\/div><\/div><\/div>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":1,"featured_media":0,"parent":8230,"menu_order":6,"comment_status":"closed","ping_status":"closed","template":"","meta":{"_acf_changed":false,"footnotes":""},"class_list":["post-9419","page","type-page","status-publish","hentry"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v18.7 (Yoast SEO v25.8) - 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